属性
折光率 1.434
密度 1.1310
沸点 86-87 °C/0.02 mmHg(lit.)
描述
产品介绍 Horner-Wittig 试剂，优先生成 (E)-α,β-不饱和酯，这种酯可与酸发生轻度皂化反应。也可用于通过还原烷基化反应合成衍生物
别名 (叔丁氧羰基)甲基膦酸二甲酯;tert-Butyl ((oxo)dimethoxyphosphino)acetate; tert-Butyl (dimethoxyphosphinyl)acetate
应用 Reactant for:
·Preparation of phosphonate terminated PPH dendrimers as anti-HIV-1 agents
·Preparation of monodehydro diketopiperazines from ketoacyl amino acid amides via acid-catalyzed cyclization
·Preparation of α,β-unsaturated esters for use in the guanidine-catalyzed oxa-Michael addition
·Preparation of myxopyronin B and desmethyl myxopyronin B analogs, with antibacterial activity and inhibitory activity against bacterial RNA polymerase
·Allylation and subsequent ring-closing metathesis in presence of Grubbs′ catalyst or intramolecular rhodium-catalyzed cyclopropanation reactions